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One of the larger coding communities out there, DevShed does it again with this thorough introduction and tutorial to PHP4. After you're finished there, you'll want to bookmark their main PHP page, which contains all sorts of extra useful tips and techniques that you'll need at some point.
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Don't be fooled by the title. This tutorial has a short introduction to the PHP language as well, but focuses on moving quickly into the MySQL arena.
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The people at PHP can create a great language, but they're not too efficient when it comes to tutoring others. This is a really, really fast tutorial that might help some more programmers already experienced in other languages, but don't count on this one as your only tutorial source.
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A very informal and friendly, but well-done PHP introduction.
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